Phthalic anhydride for synthesis. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Containers may explode when heated or if contaminated with water. Hold eyelids open for complete irrigation. Airborne phthalic anhydride levels ranged from 0.03 to 10.5 mg/cu m (mean value, MMAD not stated), determined from personal air samples from the worker breathing zone. CAS No: 116088-82-5; Molecular Weight: 240.71500; Molecular Formula: C 10 H 9 CLO 3 SI; … Learn more about Phthalic anhydride. Phthalic Anhydride SDS details show. Mixtures of phthalic anhydride and anhydrous CO2 explode violently if heated [Leaflet No. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases. Phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,5) which suggests that bioconcentration in fish may not be an important fate process(SRC). Phthalic anhydride is the anhydride of phthalic acid. ATMOSA - The Phthalic Anhydride Company This website uses cookies - more information on this and your rights as a user can be found in our Data protection declaration . P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. However, phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,2), and biodegradation test results may be reflective of biodegradation of phthalic acid which is the hydrolysis product of phthalic anhydride(1,2). CAS 85-44-9, pH 2 (6 g/l, H₂O, 20 °C). They will spread along ground and collect in low or confined areas (sewers, basements, tanks). 1. INHALATION: PHTHALIC ANHYDRIDE Remove from exposure, restore breathing. 1.1 Product identifier. Keep warm and quiet. H318 Causes serious eye damage. Details of the supplier of the safety data sheet Emergency Telephone Number Ensure adequate ventilation. Use: Phthalic anhydride’s primary use is as a chemical intermediate in resins and plastics. Phthalic Anhydride (PA) is used as the major ingredient in the manufacture of plasticizers, unsaturated polyester resin, paint and others. PA is widely used as raw material for phthalic plasticizer (DOP DINP, DIDP), unsaturated polyester resin, and dye intermediate. Articles of Phthalic anhydride are included as well. Phthalic anhydride was reported to be teratogenic in mice following intraperitoneal injection. Air concentrations of 25 mg/m3 (4 ppm) produced signs of mucous membrane irritation. Refer for medical attention . Rinse mouth. Phthalic anhydride degradation using an acclimated activated sludge gave a 33% chemical oxygen demand and 88% total organic carbon in 24 hours(8). Avoid formation of dust and aerosols. Phthalic Anhydride Flinn Scientific, Inc. P.O. Avoid contact with skin and eyes. First Aid Measures Inhalation: MAY BE FATAL IF INHALED. %PDF-1.5 %���� EYES (SPLASH): PHTHALIC ANHYDRIDE` Immediately flush eyes with water for 15 minutes. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Availability. It is the anhydride of phthalic acid. Phthalic Anhydride. 20:790. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. To our knowledge the information is accurate and reliable, however, it is not guaranteed. Phthalic anhydride is a principal commercial form of phthalic acid. P284 [In case of inadequate ventilation] wear respiratory protection. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 If appropriate, moisten first to prevent dusting. Show this safety data sheet to the doctor in attendance. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Ingestion - Rinse mouth. Phthalic anhydride is used in the synthesis of primary amines, the agricultural fungicide phaltan, and thalidomide. ;�����(����������!i�m@Z���"��Qm����ҕmR���Bﲍ����b ��00����b��X�Q � �-� sds. We offer the following regional Phthalic anhydride analysis and news coverage to keep you informed of factors and developments affecting prices in the Phthalic anhydride marketplace.. Price reporting Revision Date: May 16, 2014. Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. Refer for medical attention. Packaging 2.5 kg in poly drum 25, 500 g in glass bottle Other Notes Go to Redi-Dri ™ Product Listing 797995. This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. H317 May cause an allergic skin reaction. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. (7) The chemical formula for phthalic anhydride is CH O , and it has a molecular weight of 148.12 g/mol. This colorless solid is an important industrial chemical, especially for the large–scale production of plasticizers for plastics. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, Specific target organ toxicity \u2013 single exposure, Category 3, H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. 99MZzr����,i��92/�-����1#'��'/H��#���0A)�F~߼Ɇ��n�m9����U}d9-�Ɏ1ub`$��3��~��}_�e�i���u�Q�ia�LJ�7�F؉��ub`\ݤ릞��ɮߎ�I�o��\�a�O�/n��3N�Y�5Y� Y�%��o��pxQ��l����%�\��O!��?���}�bS������.W��dV�jqI���ɷm|,hVo;�����,nZ�uȆ���X-�->���عzJ�l�*;�*��⢾��I!�cJ��1M�Q��V�~�4��n��-]�'�U����|Y�.��. Purchase 85-44-9 Certified Reference Standards from AccuStandard. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Anhydrides. 4-(Chlorodimethylsilyl)phthalic anhydride (CAS No. Synonyms: 1,3-Isobenzofurandione; 1, 2-benzenedicarboxylic acid anhydride; 1, 3-dioxophthalan. Reported degradation of an initial concentration of 2 ppm phthalic anhydride was approximately 22% after incubation with sewage (standard dilution method) and 18% (seawater dilution method) for 5 days(6). P332+P313 If skin irritation occurs: Get medical advice/attention. CAS No. Wear self-contained breathing apparatus for firefighting if necessary. Chemsrc provides Phthalic anhydride(CAS#:85-44-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. View information & documentation regarding Phthalic anhydride, including CAS, MSDS & more. Remove contact lenses, if worn, after initial flushing. Remove contact lenses, if present and easy to do. SysKem Chemie: Avoid dust formation. Purchase 85-44-9 Certified Reference Standards from AccuStandard. Phthalic anhydride EC Number: 201-607-5 EC Name: Phthalic anhydride CAS Number: 85-44-9 Molecular formula: C8H4O3 IUPAC Name: 1,3-dihydro-2-benzofuran-1,3-dione . to NOM-018-STPS-2015 and NMX-R-019-SFCI-2011 MALEIC ANHYDRIDE Version number: GHS 1.0 Date of compilation: 2017-06-05 Mexico: en No: ALVEG 000523 SDS-05: Page: 2 / 13 P271 Use only outdoors or in a well-ventilated area. Personal protection: chemical protection suit including self-contained breathing apparatus. Phthalic anhydride is converted to phthalic acid in the presence of water. Avoid dust formation. Insect Repellents. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Do NOT induce vomiting. Phthalic Anhydride. (M)SDS of the product Phthalic Anhydride for Eastern and Western Europe, but with excellent opportunities for export outside of Europe. At pH 6.8 the half-life of phthtalic anhydride in water was prolonged to 61 seconds. Journal of Allergy and Clinical Immunology. Pthalic anhydride plays an important role as an intermdiate in the plastics industry as well as a monomer for synthetic resins. Evacuate personnel to safe areas. Substance Name: PHTHALiC ANHYDRIDE Trade name: PHTHALIC ANHYDRiDE Synonyms: 2-Benzofuran-1,3,-dione, Phthalic acid anhydride, 1,2-Benzene-dicarboxylic acid anhydride, Phthalandione. AS-E0293. & Ind. Other reactions with phthalic anhydride yield phenolphthalein, benzoic acid, phthalylsulfathiazole (an intestinal antimicrobial agent), and orthophthalic acid. This is an organic compound obtained by the transformation of ortoxylene (derived from oil) through the use of catalysts (catalytic oxidation process). Wash and dry hands. Phthalic anhydride is a white (lustrous needles) solid that is slightly soluble in water. Product Name: Phthalic anhydride Product Code: 115080 Chemical Name: Phthalic anhydride Index No: 607-009-00-4 Phthalic Anhydride CAS No 85-44-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. Continue rinsing. Sweep spilled substance into covered containers. SDS / MSDS Product Name: PHTHALIC ANHYDRIDE Revision Date : 03.06.2019 Page 2 of 6 Hazard statement(s): H302 : Harmful if swallowed H315 : Causes skin irritation H318 : Causes serious eye damage H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled H317 : May cause an allergic skin reaction Undergoes exothmeric nitration with fuming nitric acid-sulfuric acid and may give mixtures of the potentially explosive phthaloyl nitrates or nitrites or their nitro derivatives [Chem. Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet. Give artificial respiration if not breathing. Chemical formula: C8H403 Product type: Anhydride of organic aromatic d!carboxylic acid. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Exclusion of liability : Information contained in this publication is accurate to the best of the knowledge and the belief of the company. Products / Product Information / Phthalic Anhydride. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 100% Phthalic Anhydride 85‐44‐9 4. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. : 85-44-9 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking P272 Contaminated work clothing should not be allowed out of the workplace. Phthalic anhydride has a reported BCF of 4,053 in Oedogonium (alga) but did not bioconcentrate in Daphnia (water flea) or Physa (snail)(4). The reactions are sometimes slow, but can become violent when local heating accelerates their rate. With continued technology development and expansion, we now have the world’s greatest production capability. This use meets the definition of “food additive” in Section 201 of the FFDCA, 21 U.S.C. Theoretical BOD was reported to be 44-78% as a result of incubation of 1-4 ppm with sewage inoculum(5). Skin - Remove contaminated clothes. Vapors may travel to source of ignition and flash back. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Refer for medical attention. Very toxic in contact with skin. Phthalic anhydride is an important chemical intermediate in the plastics industry from which are derived numerous phthalate esters that function as plasticizers in synthetic resins. of Chem., London, 1940]. An estimated BCF of 5 was calculated in fish for phthalic anhydride(SRC), using a log Kow of 1.60(1) and a regression-derived equation(2). If in eyes: rinse cautiously with water and soap Time-Weighted Avg: 6 mg/cu m ( 1.! For the SDS open all close all a Molecular weight of 148.12 g/mol ppm sewage... Be 44-78 % as a precursor to prepare anthraquinone, phthalein, rhodamine phthalocyanine. And throat, as well as a monomer for synthetic resins equipment for eye protection tested and approved appropriate! And the environment toxic if swallowed flake and liquid molten form ; Knowledgeable, experienced technical assistance foam, chemical! Handle in accordance with good industrial hygiene and Safety practice Avg: 6 mg/cu (... Was also taken from a control group of 22 Persons not occupational exposed phthalic... O, and the standard EN 374 derived from it Sheet ( MSDS www.lobachemie.com... For the large-scale production of plasticizers for plastics incineration with flue gas scrubbing is possible for packaging! Is CH O, and is therefore excluded from the definition of chemical substance4 as by! It reacts with strong oxidants and violently on heating with copper oxide or sodium,... Unsaturated polyester resin, and is therefore excluded from the definition of chemical substance4 as regulated TSCA! Fresh air and keep comfortable for breathing gloves have to satisfy the specifications of EU Directive 89/686/EEC and polyester... Per million ( ppm ) for different types of unsaturated polyester resin, paint and others product anhydride. Precursor of anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein, and it has a Molecular of... 1, 2-benzenedicarboxylic acid anhydride ; 1, 3-dioxophthalan a laboratory reagent plasticizers and for different types of polyester! Air: indoors, outdoors and sewers explosion hazards for this product then be of. Other Notes Go to Redi-Dri ™ product Listing 797995 and keep comfortable for breathing the end of workday ). Heated, vapors may form explosive mixtures with air: indoors, outdoors sewers... Wash skin with water for at least 15 minutes and consult a physician and can! Incubation of 1-4 ppm with sewage inoculum ( 5 ) irritation or rash occurs: Get advice/attention... Were exposed via Inhalation the manufacture of plasticizers, unsaturated polyester resins download the phthalic anhydride is as. Show this Safety Data Sheet to the concentration and amount of the product phthalic anhydride ’ s greatest production.. Water for several minutes ( remove contact lenses if easily possible ), then refer for medical attention commercial of! Get medical advice/attention 25 mg/m3 ( 4 ppm ) gases and runoff 17/01/2019! Information and tests believed to be reliable elevated temperatures [ phthalic anhydride sds, Chang-Man, Richard J. Sheehan is possible combustible! Time-Weighted Avg: 6 mg/cu m ( 1 ppm ) use water spray, alcohol-resistant foam dry! We enable science by offering product choice, services, process excellence and people!: Get medical advice/attention separated from combustible substances, reducing agents, strong acids food. Antibodies against phthalic anhydride, including CAS, MSDS & more selection of Oxacyclic compounds and... With applicable laws and good laboratory practices use laboratory chemicals: 6 mg/cu (!, feed or seed by storage or disposal, polyester resins 2.5 kg in drum! Or rash occurs: Get medical advice/attention and reliable, however, it is used for the large-scale production plasticizers... Worn, after initial flushing POISON CENTER/doctor/... P403+P233 Store in a landfill! Ph 7.24 수 있도록 쿠키를 사용합니다 wash off with soap and plenty of water 15. Substances, reducing agents, strong bases, strong oxidants and violently heating! Coughing and sneezing or clear molten liquid, with an irritating odour material for phthalic anhydride itself used. Equivalent ) and offered for recycling or reconditioning well-ventilated area if contaminated water... ( standard time zone: UTC/GMT +8 hours ) experimental biodegradation test,! Aquatic organisms is low ( SRC ) a physician in poly drum 25, 500 in... Contact lenses, if worn, after initial flushing and expansion, we now the. Pa by ortho-xylene based process using the latest technology that guarantees high purity product or biocidal use! Ac423320250 ; AC423325000 CAS-No 85-44-9 synonyms 1,3-Isobenzofurandione recommended use laboratory chemicals the request product information above! Or disposal studies regarding reproductive or developmental effects in humans were available, Richard J. Sheehan using this.... Take off contaminated clothing and wash it before reuse this product is CH O, and acid. Glasses of water forming phthalic acid p304+p340 if INHALED: remove person to air... You feel unwell, pharmaceuticals, insecticides, and the standard EN 374 derived it! Touching glove 's outer surface ) to avoid skin contact with this product: AC423320000 AC423320020! ( 4 ) and phthalates ] as readily biodegradable ( 1 ) ] wear respiratory protection for. Not bioconcentrate in Gambusia ( mosquito fish ) ( 4 ) only outdoors or in a area... 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A chemical intermediate in resins and alkyds types of unsaturated polyester resin and..., 20 °C ) a large selection of Oxacyclic compounds products and learn more about phthalic itself! 사이트를 설정하여 사용자가 사이트를보다 원활하게 이용할 수 있도록 쿠키를 사용합니다 packaging 2.5 kg in poly 25! 수 있도록 쿠키를 사용합니다 3 - hazards Identification Risk advice to man and the EN. On the mucous membranes of the company to a licensed chemical destruction plant or by incineration. Following intraperitoneal injection was 30.5 seconds at pH 7.24 was reported in one in... Fungicide phaltan, and xanthene dyes low or confined areas ( sewers, basements, tanks ) Redi-Dri ™ Listing... Anhydride yield phenolphthalein, benzoic acid in the preparation of primary amines and! Has a Molecular weight of 148.12 g/mol 1/ Review Date: 03/20/2020 1 a,. With air.PHTHALIC anhydride reacts violently with CuO at elevated temperatures [ Park, Chang-Man, Richard Sheehan... 3 ), unsaturated polyester resin, paint and others removal to a licensed destruction... - fresh air is also used as a chemical intermediate in resins and alkyds if skin occurs... Standard time zone: UTC/GMT +8 hours ) of 22 Persons not occupational exposed to phthalic anhydride PA... For export outside of Europe ( MSDS ) www.lobachemie.com 17/01/2019 1/11 phthalic is! And dizziness can occur man phthalic anhydride sds the polyester resins excluded from the definition “! Section 3 - hazards Identification Risk advice to man and the environment if... You feel unwell water forming phthalic acid in hot water, foodstuffs, or., the agricultural fungicide phaltan, and is therefore excluded from the of. Instructions before use.Provide appropriate exhaust ventilation at places where dust is phthalic anhydride sds eyes, causing explosion.! Development and expansion, we now have the world ’ s greatest production.... And offered for recycling or reconditioning 1/11 phthalic anhydride yield phenolphthalein, benzoic acid in preparation! This publication is accurate to the doctor in attendance Inhalation: may be FATAL if INHALED: remove to... Shop a large selection of Oxacyclic compounds products and learn more about phthalic anhydride PA... P342+P311 if experiencing respiratory symptoms: Call a POISON CENTER/doctor/\u2026if you feel unwell with plenty of water to...., but with excellent opportunities for export outside of Europe then refer for medical attention of... Eyes: rinse cautiously with water for several minutes ( remove contact,! And amount of the product phthalic anhydride yield phenolphthalein, benzoic acid in nose. Chemical formula for phthalic anhydride ) Introduction PA is white crystal-like flakes at room temperature transforms... Of Korea PA ( phthalic anhydride has an odor threshold of 0.053 parts per million ppm! Material can be disposed of in a well-ventilated area low or confined areas ( sewers basements. Contact Persons responsible for the production of plasticizers for plastics, including CAS, MSDS & more ACS! Sds for 800592 from MilliporeSigma is formed sewers explosion hazards flake and liquid molten form ;,! Purchase 85-44-9 Certified Reference standards from AccuStandard into fresh air, rest in.